You assign them while she is pregnant. There is a menue that will appear and allow you to choose between warrior/defender/scout/harvester, and to assign bugs that have those pheremones ready.
I can't figure out how to embed an image, but hopefully this link will work.
https://imgur.com/oVimAdy
See "Use Pheremones" at bottom left? That's what you need to use.
You can't assign the mother to her own baby, and you can't assign a throdama that is busy with anything--they have to be active, and assigning them will keep them busy until the baby grows up.
